Accurate waste determinations are the first step in ensuring safe management of hazardous waste.
Waste Determination Process:
There are five principal steps in the waste determination process:
- Identify the waste streams
- Determine whether the waste stream is a solid waste
- Determine if the solid waste is excluded
- Determine whether the solid waste is a hazardous waste under NR 662.011
- Document the information in steps 1-4: Compile the information used to make the waste determination, including a statement on whether the waste is a hazardous waste. If it is hazardous waste, list the applicable waste codes (D001, F003, U183, etc.) and what the generation rate of this waste is per month.
Listed or Characteristic Hazardous Wastes:
Hazardous wastes can be process wastes, chemicals or compounds designated as "listed wastes" and/or they can exhibit hazardous characteristics (ignitability, corrosivity, reactivity or toxicity). The waste codes outlined below are used to identify and track the wastes on shipping manifests.
Listed Wastes
F-list wastes:
These waste types (F001-F039) typically include certain spent solvents, paint thinners, brake and carburetor cleaners, vapor degreasing and dry cleaning solvents, electroplating wastes, and manufacturing and process wastes. [NR 661.31]
K-list wastes
These waste types (K001-K178) typically come from specific sources such as industrial processes like wood preserving, manufacturing pesticides, organic chemicals and veterinary drugs. [NR 661.32]
P-list wastes
These wastes are identified as acute hazardous wastes (P001-P205) and include discarded commercial chemical products; off-specification species; container and spill residues including unused chemicals such as cyanides, arsenic compounds and several pesticides. These wastes are extremely dangerous to human health and the environment in very small doses or short-term exposure. [NR 661.33]
U-list wastes
These wastes are identified as toxic wastes (U001- U411) and include discarded commercial chemical products, off-specification species, container residues, and spill residues including used chemicals that pose health risks due to their persistence in the environment or their potential for migrating through the environment. These wastes are dangerous to humans and the environment in small doses, but are not as toxic as "P listed" wastes. [NR 661.34]
Characteristic Wastes
Waste Code D001
Ignitability represents the ability of the waste to burn. Liquid wastes are ignitable if their flash point is less than 140 degrees F. Some non-liquids, flammable gases and certain oxidizers also have this characteristic. [NR 661.21]
Liquid wastes w/flash point <140F |
Gasoline, xylene, toluene, acetone, benzene, methanol, isopropyl alcohol |
Non-liquids |
sulfer, oily rag containing drying oils (linseed oil, soya bean oil, tung oil), wetted titanium powder, aluminum powder, magnesium powder, alkali metals |
Flammable gases |
Propane, acetylene, butane, hydrogen, methane. |
Oxidizers |
Chlorates, permanganates, inorganic peroxides, organic peroxides, nitric acid in concentrations from 65% to 70%. |
Flammable Oxidizing Compressed Gas
Waste Code D002:
Corrosivity represents the ability of the waste to destroy or deteriorate materials, chemically burn skin, enhance movement of toxic chemicals in the environment, react dangerously with other wastes, or harm fish and other aquatic life. Aqueous wastes (>50% water) are corrosive if their pH is less than or equal to 2 or greater than or equal to 12.5 (e.g., rust remover, descaling products). Liquid wastes (e.g., ferric chloride) are corrosive if they corrode steel by more than one-quarter inch per year. [NR 661.22]
Corrosive
Waste Code D003:
Reactivity is the waste’s tendency to react violently or explode. Wastes are reactive if they are unstable either alone or in the presence of water. These wastes can form explosive mixtures with water and produce dangerous quantities of toxic gases, vapors or fumes when mixed with water or when exposed to mild acids or bases. They can detonate, react or decompose explosively (e.g., hydrogen sulfide, cyanide or sulfide-bearing wastes, lithium-sulfur batteries, nitroglycerin formulations, ethylene oxide, sodium azide, and phosphorous). [NR 661.23]
Explosive
Waste Code D004 - D043:
Toxicity is the ability of hazardous constituents to leach out of the waste. Wastes are toxic if they release or leach any of 39 specified heavy metals, pesticides or other organic chemicals above their regulatory level concentrations (e.g., benzene, carbon tetrachloride, chromium, Chlordane, Endrin, lead, mercury). [NR 661.24]
Toxic Health hazard
See WI DNR WA 1152 Waste Determination and Recordkeeping for more details.